jos-Error: Application Instantiation Error

JFactory :: getApplication() @ /var/www/nansmit/data/www/nansmit.org/index.php:36
JApplication :: getInstance() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/factory.php:102
JSite -> __construct() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/application/application.php:180
JApplication -> __construct() @ /var/www/nansmit/data/www/nansmit.org/includes/application.php:47
JApplication -> _createSession() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/application/application.php:145
JFactory :: getSession() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/application/application.php:1017
JFactory :: createSession() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/factory.php:152
JSession :: getInstance() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/factory.php:661
JSession -> __construct() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/session/session.php:151
JSession -> _start() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/session/session.php:114
session_start() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/session/session.php:532
JSessionStorageDatabase -> read()
JFactory :: getDbo() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/session/storage/database.php:34
JFactory :: createDbo() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/factory.php:308
JDatabase :: getInstance() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/factory.php:710
JDatabaseMySQLi -> __construct() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/database/database.php:328
JText :: _() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/database/database/mysqli.php:110
JFactory :: getLanguage() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/methods.php:133
JFactory :: createLanguage() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/factory.php:172
JLanguage :: getInstance() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/factory.php:823
JLanguage -> __construct() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/language/language.php:270
JLanguage -> setLanguage() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/language/language.php:174
JLanguage :: getMetadata() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/language/language.php:1231
JLanguage :: parseXMLLanguageFile() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/language/language.php:1171
JFactory :: getXML() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/language/language.php:1402
JError :: raiseWarning() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/factory.php:455
JError :: raise() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/error/error.php:276
JError :: throwError() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/error/error.php:176
call_user_func_array() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/error/error.php:214
JError :: handleMessage()
JFactory :: getApplication() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/error/error.php:705
JError :: raiseError() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/factory.php:99
JError :: raise() @ /var/www/nansmit/data/www/nansmit.org/libraries/joomla/error/error.php:251Database connection error (2): JLIB_DATABASE_ERROR_CONNECT_MYSQL